改性褐煤吸附土壤中重金属铅和镉的实验

    Adsorption of Heavy Metals Lead and Cadmium in Soil by Modified Lignite

    • 摘要: 该论文以揭示改性褐煤对土壤中重金属Pb2+和Cd2+的吸附效果及解析机制为研究目的。研究方法:对比褐煤磺化前后微观结构的形貌变化;设计4个单因素梯度变量(pH值、褐煤投加量、吸附时间、吸附温度)开展磺化前后的吸附对比实验;测定不同pH值梯度下改性褐煤对土壤Pb2+和Cd2+的解吸效应。结果显示:改性前后褐煤比表面积由165 m2/g上升至784 m2/g;改性褐煤对Pb2+、Cd2+吸附率与溶液的pH值、褐煤投加量、吸附时间、吸附温度均呈正相关;改性褐煤投放量为6%时单位质量吸附剂的去除率达到最大;吸附时间在120 min时达到吸附平衡;当pH值为11时,改性褐煤对Pb2+和Cd2+的解吸量较低,且吸附有较高的稳定性。因此,改性褐煤较改性前对土壤重金属铅和镉吸附效率提高,可作为土壤重金属污染治理的添加材料。

       

      Abstract: In this paper, the adsorption and resolution mechanism of heavy metals Pb2+ and Cd2+ by modified lignite were studied. Methods: Four single-factor gradient variables (pH value, amount of lignite, adsorption time, adsorption temperature) were designed to carry out the adsorption contrast test before and after the sulfonation. The desorption effects of modified lignite on Pb2+ and Cd2+ in soil were measured at different pH value gradients. The results showed that the specific surface area of lignite increased from 165 m2/g to 784 m2/g, and the adsorption rate of Pb2+ and Cd2+ on modified lignite was positively correlated with pH value of solution, addition of lignite, adsorption time and adsorption temperature The adsorption equilibrium was reached at 120 min when the dosage of modified lignite was 6%, and the desorption of Pb2+ and Cd2+ was the lowest when pH value was 11, and the adsorption has high stability. Conclusions: the adsorption efficiency of modified lignite on heavy metals Pb2+ and Cd2+ in soil is higher than that before modification, and it can be used as an additive material for the treatment of heavy metal pollution in soil.

       

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