洗-浮结合综合回收高密度废钻井液中重晶石工艺

    Integrated Recovery of Barite from High-density Waste Drilling Fluids by Washing-floating Process

    • 摘要: 【目的】油气行业的万米超深井钻探已逐步成为现实,超高密度钻井液对加重剂需求很大。为回收返排废钻井液中蕴含的加重剂固相,节约成本的同时处理固废,保护环境,【方法】利用“清洁破胶+高速水洗”工艺富集废钻井液中重晶石,随后采用反浮选法对无用固相进行脱除,设计并优化相应回收工艺。【结果】以固液比1∶2、转速1 000 r/min、清洁型破胶剂YJ-1单次加量为5‰条件下可得密度为4.127 g/cm3的优品重晶石;采用“一粗二精一扫”浮选工艺,捕收剂十二烷基硫酸钠用量为700 g/t、食物凝胶型抑制剂结冷胶用量为700 g/t,可得综合回收率为81.86%、综合品位≥92%、混合精矿密度≥4.2 g/cm3的重晶石混合精矿。【结论】该方法药剂清洁、流程简洁、回收重晶石品质优,或可为油气田井场废钻井液中重晶石回用提供一定借鉴思路。

       

      Abstract: Objective The drilling of ultra-deep wells over 10,000 meters in the oil and gas industry has gradually become a reality, and there is a great demand for weighting agents in ultra-high density drilling fluids. To recover the solid phase of weighting agents contained in the returned waste drilling fluid, save costs while treating solid waste and protecting the environment, Method the ‘clean gel breaking + high-speed water washing’ process is utilized to enrich barite in the waste drilling fluid. Subsequently, the reverse flotation method is adopted to remove the useless solid phase. The corresponding recovery process is designed and optimized. Results At the conditions of a solid-liquid ratio of 1∶2, a rotational speed of 1,000 r/min, and a single addition of the cleaning gel breaker YJ-1 at 5‰, high-quality barite with a density of 4.127 g/cm3 can be obtained. By adopting the "one coarse, two fine and one sweep" flotation process, with the collector sodium dodecyl sulfate dosage of 700 g/t and the food gel-type inhibitor gellan gum dosage of 700 g/t, a barite mixed concentrate with a comprehensive recovery rate of 81.86%, a comprehensive grade of ≥ 92%, and a mixed concentrate density of ≥4.2 g/cm3 can be obtained. Conclusion The method is characterized by clean pharmaceuticals, simple process and excellent quality of recovered barite, which may provide some ideas for the reuse of barite from waste drilling fluids in the oil and gas field wells.

       

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