低共熔溶剂在废锂离子电池回收中的研究进展

    Research Progress of Deep Eutectic Solvents in the Recycling of Spent Lithium-ion Batteries

    • 摘要: 随着电动汽车、储能等产业的快速发展,锂离子电池需求快速增长,随之而来其报废量也日益增长,高效资源化回收废旧锂离子电池成为我国目前亟须解决的重大问题。废旧锂离子电池目前主要采用的火法冶金、湿法冶金和修复再生等方法都存在各自的不足,亟须更加绿色高效的回收处理方法。低共熔溶剂因具备热稳定性、易合成和毒性弱等优点,在废锂离子电池回收方面展现出独特优势。详细介绍了低共熔溶剂在废旧锂离子电池正极材料浸出、解离和修复再生方面的研究进展,阐述了有价金属的浸出机理,最后展望了低共熔溶剂在废旧锂离子电池资源化回收方面的发展趋势。

       

      Abstract: With the rapid development of electric vehicles, energy storage and other industries, the demand for lithium-ion batteries is growing rapidly, and the amount of their disposal is also increasing, and the efficient resource recovery of spent lithium-ion batteries has become a major problem that needs to be solved in China. The current methods of pyrometallurgy, hydrometallurgy and repair and regeneration of spent lithium-ion batteries have their own shortcomings, and there is an urgent need for greener and more efficient recycling and treatment methods. Deep eutectic solvents have unique advantages in the recycling of spent lithium-ion batteries due to their thermal stability, easy synthesis and low toxicity. In this paper, the research progress of deep eutectic solvents in leaching, dissociation and repair and regeneration of cathode materials of spent lithium-ion batteries is introduced in detail, the leaching mechanism of valuable metals is elaborated, and finally the development trend of deepeutectic solvents in the resource recycling of spent lithium-ion batteries is anticipated.

       

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