激光拉曼光谱mapping成像技术在矿物鉴定中的应用研究

    Application of Laser Raman Spectral Mapping in Mineral Identification

    • 摘要: 【目的】矿物鉴定是各项地质工作开展的基础,但传统鉴定受人员经验影响较大,具有较强的主观性。【方法】以不同类型的岩石光薄片样品和单矿物样品为研究对象,通过激光拉曼光谱mapping技术进行大面积扫谱,研究该方法在矿物鉴定中的实际应用效果,从实验模式的选择、实验条件的设置到最终成像,围绕整个测试过程,分析制约该技术实际应用的若干因素,提出实验条件的设置原则,探讨该技术在矿物类鉴定中的适用领域,并对未来发展提出了建议。【结果】与传统鉴定相比,该技术分辨微细矿物的能力更强,精确度高,其组分化学成像图能直观地了解各类矿物的组成和分布情况,在单矿物中还可以进行各类含量的统计。并认为样品类型是影响成像的主要因素,实验条件设置是次要因素,需要在大规模扫谱前予以确定。其中成像区域划定、曝光时间长短、采集步长间隔、采集点位的设置需结合样品类型特点考虑,测试精度直接影响成像效果,但又与测试时间成反比,要平衡两方面的需求,还需要结合样品实际情况选择。而面对包含多矿物混合峰位、蚀变矿物、类质同象类、同族变种矿物的拉曼光谱图,人员的解谱能力和鉴定能力也不可或缺。【结论】经分析,该技术的点模式适合单矿物这类颗粒零散的矿物;线模式适合具有层次性的样品,如板岩等;范围模式对成分均匀、粒径大小均匀且蚀变较小的矿物类样品更为适用。该技术经与镜下鉴定方法结合,可为矿物鉴定提供一种更准确、直观和方便的研究手段。

       

      Abstract: Objective Mineral identification is the basis of geological work, but the traditional identification is greatly affected by the experience of personnel and has strong subjectivity. Method This article takes different types of rock light thin slice samples and single mineral samples as research objects, and uses laser Raman spectral mapping technology to conduct large-area spectrum scanning to study the practical application effect of this method in mineral identification. From the selection of experimental mode, the setting of experimental conditions to the final imaging, several factors restricting the practical application of this technology are analyzed around the entire testing process. The principle of setting experimental conditions is put forward, the application field of the technique in mineral identification is discussed, and some suggestions for future development are put forward. Result Compared with the traditional identification, the technology has a stronger ability to distinguish fine minerals and a higher accuracy. The chemical imaging map of its components can intuitively understand the composition and distribution of various minerals, and can also carry out statistics of various contents in single minerals. It is considered that sample type is the main factor affecting imaging, and experimental conditions are secondary factors, which should be determined before large-scale scanning. Among them, the delineation of the imaging area, the length of exposure time, the collection step interval, and the setting of the collection point should be considered in combination with the characteristics of the sample type. The test accuracy directly affects the imaging effect, but it is inversely proportional to the test time. In order to balance the needs of the two aspects, it is also necessary to combine the actual situation of the sample. In the face of Raman spectra containing multi-mineral mixed peaks, altered minerals, homomorphic and homologous minerals, the ability of spectral resolution and identification of personnel is also indispensable. Conclusion The analysis shows that the point model of the technique is suitable for single minerals with scattered particles. The linear model is suitable for layered samples, such as SLATE. The range model is more suitable for mineral samples with uniform composition, uniform particle size and small alteration. The technique, combined with the microscopic identification method, can provide a more accurate, intuitive and convenient research method for mineral identification.

       

    /

    返回文章
    返回