低品位氟碳铈矿型萤石资源回收工艺研究进展

    Advances in Beneficiation Processes for Low-grade Bastnaesite-associated Fluorite Resources

    • 摘要: 萤石作为制备含氟化合物的战略性资源,被中国、美国、欧盟列为关键矿产,其高效回收对保障资源安全至关重要。我国氟碳铈矿型萤石资源主要赋存于白云鄂博、牦牛坪等稀土矿床,具有“低品位、细粒嵌布、矿物共生复杂”的特点,传统分选技术面临稀土-萤石可浮性相近、药剂选择性差等挑战。本文系统梳理了氟碳铈矿型萤石的资源分布与工艺矿物学特征,重点评述了选矿技术进展:(1)开发新型抑制剂(CMK-2、DC-2)与捕收剂(MQY、CXS-211),实现萤石与重晶石、方解石的高效分离,精矿品位提升至90.8%;(2)白云鄂博创新采用“磁-浮-浸”联合工艺,萤石回收率达72.5%;(3)稀土尾矿“浮选脱硫-混合浮选-磁选分离”协同回收模式,大陆槽尾矿萤石回收率突破50.0%。工业实践表明,靶向分选与流程强化可显著提升资源利用率。未来需聚焦短流程低温分选技术及尾矿建材化等绿色路径,推动氟碳铈矿型萤石资源向“近零废弃”目标迈进。

       

      Abstract: Fluorite as a strategic resource for preparing fluorine-containing compounds, has been designated as a critical mineral by China, the United States, and the European Union. Its efficient recovery is vital for ensuring resource security. In China, bastnaesite type fluorite resources are primarily formed in rare earth deposits such as the Bayan Obo and Maoniuping regions, characterized by "low-grade, fine-grained dissemination, and complex mineral paragenesis". Traditional separation technologies face challenges due to the similar floatability of rare earth minerals and fluorite, as well as the poor selectivity of conventional reagents. This paper systematically reviews the resource distribution and process mineralogical characteristics of bastnaesite-type fluorite, with a focus on advancements in beneficiation technologies: (1) Development of novel inhibitors (CMK-2, DC-2) and collectors (MQY, CXS-211) has enabled efficient separation of fluorite from barite and calcite, achieving concentrate grade improvement to 90.8%; (2) In the innovative "magnetic-flotation-leaching" integrated process such as Bayan Obo "weak magnetic iron removal - rare earth flotation - fluorite selection" process, the fluorite recovery rate has reached 72.5%; (3) A collaborative recovery model of "flotation and desulfuration - mixed flotation - magnetic separation" for rare earth tailings was proposed, achieving fluorite recovery rate up to 50.0% from continental geosyncline tailings. Industrial practices demonstrate that targeted separation and process intensification significantly enhance resource utilization efficiency. Future efforts should prioritize green pathways such as short-process low-temperature separation and tailings for building materials, to advance bastnaesite type fluorite resource utilization toward a "near-zero waste" objective.

       

    /

    返回文章
    返回