含锂高岭土浮选尾矿制备陶瓷及其性能研究

    Porcelain Performance of Floatation Tailings Containing Lithium Kaolinite

    • 摘要: 【目的】宜春某矿业公司含锂高岭土矿浮选尾矿以石英、钠长石为主,满足制备陶瓷原料的条件,可以烧制陶瓷。【方法】对该含锂高岭土浮选尾矿进行了元素成分、矿物组成等分析,原矿、浮选尾矿及浮选尾矿经磁选后的磁性产品和非磁性产品通过XRD分析,经磁选除杂后,各组分的主要矿物成分仍为石英及钠长石,且非磁性产品中杂质Fe2O3明显减少。【结果】通过开展日用陶瓷胚釉料配方烧成试制,结果表明经磁选处理过后的尾矿,配以其他原料,烧成终止温度1 070 ℃,在ZP.M18/B 人工智能电阻炉内,常压氧化气氛下,烧成周期6 h,可获得白度72%,光泽度83%,吸水率0.4%,抗热震性180~20 ℃热交换一次均未裂,各项指标均符合国家标准。【结论】为同类型尾矿资源的综合化、高效化利用提供了一定的参考价值。

       

      Abstract: Objective The flotation tailings of the lithium-containing kaolin mine of a certain mining company in Yichun mainly consist of quartz and albite, which meets the conditions for preparing ceramic raw materials and can be used for firing ceramics. Method The elemental and mineral compositions of the lithium-containing kaolin flotation tailings were analyzed. The raw ore, flotation tailings, and the magnetic and non-magnetic products of the flotation tailings after magnetic separation were analyzed by XRD. After magnetic separation and impurity removal, the main mineral components of each component were still quartz and albites, and the impurity Fe2O3 in the non-magnetic products was significantly reduced. Result The tailings after magnetic separation treatment, combined with other raw materials, firing end temperature 1 070 ℃, ZP.M18/B artificial intelligence resistance furnace, atmospheric oxidation atmosphere, firing period of 6 h, can obtain 72% whiteness, 83% gloss, water absorption of 0.4%. Thermal shock resistance 180~20 ℃ heat exchange once did not crack, all indicators are in line with national standards. Conclusion It provides a certain reference value for the integrated and efficient utilization of the same type of tailings resources.

       

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