四川锂辉石尾矿工艺矿物学及锂的赋存状态

    Process Mineralogy and Occurrence State of Lithium of Spodumene Tailings in Sichuan Province

    • 摘要: 这是一篇工艺矿物学领域的文章。研究对象为四川李家沟和甲基卡尾矿,对其采用光学显微镜砂光薄片鉴定,人工重砂研究(分离、鉴定等),光普半定量分析、化学分析,MLA矿物自动定量检测,LA-ICPMS矿物微量元素原位分析,电子显微镜能谱分析,X-射线粉晶衍射等分析手段。对尾矿的化学成分、矿物成分、锂的赋存状态进行了研究。结果显示:(1)李家沟、甲基卡两处不同地区的尾矿,其Li2O品位为0.44%~0.64%,都在边界品位附近,均可再次选矿富集;伴生有价元素主要是铌、钽、铍、铷含量都未达到综合回收利用标准。(2)两处不同地区尾矿中,再次选矿富集回收利用的主要为锂辉石;伴生的微量有用矿物主要为微量铌铁矿-钽铁矿系列矿物、绿柱石,而铷主要以分散状态赋存于锂白云母和钾长石中。(3)尾矿主要回收目标矿物为锂辉石,精矿产品中Li2O的理论品位为7.33%,李家沟、甲基卡精矿理论回收率分别为86.14%、87.87%。4.尾矿人工重砂实验显示,粗粒级中Li2O含量、分布率、产率较高,而在细粒级较低。

       

      Abstract: This is an article in the field of process mineralogy. The study objects are Lijiagou and Jiajika tailings, Sichuan Province. The samples were identified by optical microscopy, artificial heavy sand research (separation, identification, etc.), optical semi-quantitative analysis, chemical analysis, MLA automatic quantitative detection of minerals, LA-ICPMS in-situ analysis of mineral trace elements, and electron microscope energy spectrum analysis, X-ray powder crystal diffraction analysis and other work. The chemical mineral composition and lithium occurrence state of the tailings were studied. The results are as follows: 1. The Li2O grade of the tailings from Lijiagou and Jiajika is 0.44%~0.64%, both of which are near the boundary grade and can be re-enriched. The content of associated valuable elements such as niobium, tantalum, beryllium and rubidium does not meet the comprehensive recycling standard. 2. In the tailings from two different areas, the main material for reconcentration and recycling is spodumene and the associated trace useful minerals are mainly trace niobite-tantalite series minerals and beryl, while rubidium mainly exists in dispersed state in lithium Muscovite and potassium feldspar. 3. The main recovery target mineral of tailings is spodumene, the theoretical grade of Li2O in concentrate products is 7.33%, and the theoretical recovery rates of Lijiagou and Jiajika card concentrate are 86.14% and 87.87%, respectively. 4. The artificial heavy sand test of tailings shows that the content, distribution rate and yield of Li2O are high in the coarse grade, but low in the fine grade.

       

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